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. 2014 Apr 4;10:784–793. doi: 10.3762/bjoc.10.74

Table 1.

Yields of products of the reaction of furan-2,3-dione 1a and azirine 2a in boiling benzene solution for 0.5 h according to 1H NMR.

Ratio 2a:1a Conversion of 2a (%) Yieldsa of 3a, 4a, 5a, % Overall yieldsa of 3a–5a, %

1:2 100 2, 16, 9 27
1:1.5 89 5, 22, 17 44
1:1 42 19, 37, 15 71
1.5:1 57 2, 19, 11 32
2:1 43 4, 20, 13 37

aYield based on consumed azirine 2a.