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. 2014 Feb 24;27(4):483–489. doi: 10.1021/tx400256b

Table 1. EPR Hyperfine Coupling Constants for Methyleugenol Radical Cation and Related Radicals.

graphic file with name tx-2013-00256b_0009.jpg

compd R1 R2 aR2a,b aOCH3 a3 aR1 a5 a6
methyleugenol CH2=CH–CH2- CH3- 0.167c (3H) 0.169c (3H) 0.025 0.794 (2H) 0.416 ∼0
3,4-dimethoxy-toluene CH3- CH3- 0.282c (3H) 0.335c (3H) 0.073 0.808 (3H) 0.498 ∼LWd
eugenol CH2=CH–CH2- H- ---e
[---]f
0.163 (3H)
[0.162]
0.181
[0.19]
0.790 (2H)
[0.797]
0.411
[0.415]
∼LW
[---]
2-methoxy-4-methylphenol CH3- H- --- 0.169 (3H) 0.153 1.032 (3H) 0.408 0.026
a

Coupling constants are in mT (1 mT = 10 gauss).

b

Numbers in parentheses are numbers of equivalent hydrogen atoms contributing to the stated hyperfine coupling.

c

Coupling constants assigned arbitrarily and may be interchanged.

d

Coupling constants were not resolved and are less than the linewidths of EPR lines, ca. < 0.020 mT.

e

Coupling constants were not observed or not reported.

f

Coupling constants in square brackets are literature values reported by ref (26).