Table 1. Spectroscopic and Electrochemical Data for the Ni–CODHs from Different Sources.
A-cluster |
B-cluster |
C-cluster |
||||
---|---|---|---|---|---|---|
g-values (−CO) | E0′ | g-values | E0′ | g-values | E0′ | |
R. rubrum(74,89) | 2.04, 1.94, 1.89 | –418 | 2.03, 1.88, 1.71 | –110 | ||
1.97, 1.87, 1.75 | ||||||
C. hydrogenoformans(88) | 2.04, 1.93, 1.89 | 2.01, 1.89, 1.73 | ||||
1.96, ?, 1.77 | ||||||
M. thermoaceticum(79b) | 2.08, 2.07, 2.03 | 2.04, 1.94, 1.90 | –440 | 2.01, 1.81, 1.65 | –220 | |
2.06, 2.05, 2.03 | –530 | 1.97, 1.87, 1.75 | –530 | |||
M. thermoaceticum with azide90 | 2.34, 2.07, 2.03 | |||||
2.34, 2.11, 2.04 | ||||||
M. barkeri(91) | 2.05, 1.94, 1.90 | –390 | 2.01, 1.91, 1.76 | –35 | ||
?, ?, 1.73 | ||||||
M. soehngenii(92) | 2.05, 1.93, 1.86 | –410 | 2.01, 1.89, 1.73 | –230 | ||
M. thermophila(93) | 2.06, 2.05, 2.03 | 2.04, 1.93, 1.89 | –444 | 2.02, 1.87, 1.72 | –154 | |
?, ?, 1.79 |