. 2014 Jan 28;136(7):2699–2702. doi: 10.1021/ja410240c

Table 1. Second-Order Rate Constants for OAT of Various Fe^IV(O) Complexes to Thioanisole.

complex	k (M^–1 s^–1)	T (°C)	ref
[Fe^IV(O)(N3Py^amideSR)]²⁺	4.3	–40	this work
[Fe^IV(O)(N4Py)]²⁺	8.7 × 10^–1	25	(10a)
(+HClO₄)	(1.5 × 10³)
[(Fe^IV(O)(N4Py)]²⁺	6.5 × 10^–2	0	(10b)
[Fe^IV(O)(TMC)]²⁺	2.9 × 10^–2	35	(10a)
[Fe^IV(O)(TPA)]²⁺	4.4 × 10^–1	–45	(10b)
[Fe^IV(O)(TBC)]²⁺	3.5 × 10^–1	–10	(10c)

Table 1. Second-Order Rate Constants for OAT of Various FeIV(O) Complexes to Thioanisole.