Table 1. Intramolecular Pd-Catalyzed Alkene Carboamination Reactions^a.

^aConditions: 1.0 equiv of substrate, 2.0 equiv of NaO^tBu, 2 mol % Pd₂(dba)₃, 8 mol % PCy₃·HBF₄, toluene (0.1 M), 105 °C.

^bIsolated yields (average of two or more experiments).

^cThis compound contained ca. 25% of an inseparable impurity tentatively assigned as 6-methyl-11-methylene-5,6,11,12-tetrahydrodibenzo[b,f]azocine, which results from competing intramolecular Heck arylation of the substrate.