Table 1.
Sugar residue | C-1; H-1 | C-2; H-2 | C-3; H-3 (H-3a,3e) | C-4; H-4 | C-5; H-5 | C-6; H-6 (H-6a,6b) | C-7; H-7 (H-7a,7b) | C-8; H-8 (H-8a,8b) |
---|---|---|---|---|---|---|---|---|
β-Glcp-(1→ | 103.7; 4.55 | 74.9; 3.32 | 76.7; 3.52 | 71.2; 3.37 | 77.5; 3.47 | 62.7; 3.97, 3.74 | ||
α-ldHepp6P-(1→ | 102.5; 5.34 | 70.9; 4.15 | 71.5; 3.91 | 67.2; 3.91 | 72.4; 3.79 | 74.6; 4.57 | 62.5; 3.76, 3.85 | |
→3,4)-α-ldHepp-(1→ | 102.2; 5.08 | 71.4; 4.17 | 74.8; 4.15 | 74.9; 4.26 | 72.5; 4.15 | 69.5; 4.13 | 64.4; 3.72, 3.74 | |
→5)-α-Kdop | n.f. | 97.0 | 35.4; 2.11, 1.94 | 67.0; 4.12 | 75.9; 4.12 | 72.3; 3.88 | 70.3; 3.70 | 64.4; 3.81, 3.65 |
NH2CH2CH2O- | 63.3; 4.17 | 41.2; 3.31 |
Assignment was performed using a two-dimensional 1H, 13C-HSQC experiment. n.f., not found. The 31P NMR signal is at δ 0.5.