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. 2014 Apr 21;15(4):6689–6702. doi: 10.3390/ijms15046689

Table 1.

1H- and 13C-NMR chemical shifts (δ, ppm) of the modified core OS from K. pneumoniae 52145ΔwabG plus pBAD18-Cm-eptC.

Sugar residue C-1; H-1 C-2; H-2 C-3; H-3 (H-3a,3e) C-4; H-4 C-5; H-5 C-6; H-6 (H-6a,6b) C-7; H-7 (H-7a,7b) C-8; H-8 (H-8a,8b)
β-Glcp-(1→ 103.7; 4.55 74.9; 3.32 76.7; 3.52 71.2; 3.37 77.5; 3.47 62.7; 3.97, 3.74
α-ldHepp6P-(1→ 102.5; 5.34 70.9; 4.15 71.5; 3.91 67.2; 3.91 72.4; 3.79 74.6; 4.57 62.5; 3.76, 3.85
→3,4)-α-ldHepp-(1→ 102.2; 5.08 71.4; 4.17 74.8; 4.15 74.9; 4.26 72.5; 4.15 69.5; 4.13 64.4; 3.72, 3.74
→5)-α-Kdop n.f. 97.0 35.4; 2.11, 1.94 67.0; 4.12 75.9; 4.12 72.3; 3.88 70.3; 3.70 64.4; 3.81, 3.65
NH2CH2CH2O- 63.3; 4.17 41.2; 3.31

Assignment was performed using a two-dimensional 1H, 13C-HSQC experiment. n.f., not found. The 31P NMR signal is at δ 0.5.