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. Author manuscript; available in PMC: 2015 Feb 7.
Published in final edited form as: J Org Chem. 2014 Jan 21;79(3):888–900. doi: 10.1021/jo401744b

Table 3.

Cross- and Ring-Closing Metathesis: Nok vs. TPGS-750-M

graphic file with name nihms558965u3.jpg
Entry Alkene Partner Product TPGS-750-M yield(%)a Nok yield(%)a Time (h)
1b graphic file with name nihms558965t1.jpg graphic file with name nihms558965t2.jpg graphic file with name nihms558965t3.jpg 72 74 12
2c graphic file with name nihms558965t4.jpg graphic file with name nihms558965t5.jpg graphic file with name nihms558965t6.jpg 89 86 12
3c graphic file with name nihms558965t7.jpg graphic file with name nihms558965t8.jpg graphic file with name nihms558965t9.jpg 81 84 24
4d graphic file with name nihms558965t10.jpg graphic file with name nihms558965t11.jpg 81 88 6
5d graphic file with name nihms558965t12.jpg graphic file with name nihms558965t13.jpg 98 96 18
a

Isolated yield of chromatographically pure materials.

b

Conditions: alkene (0.5 mmol, 1 equiv), MVK (1.5 mmol, 3 equiv).

c

Reaction: alkene (0.5 mmol, 1 equiv), acrylate (1.0 mmol, 2 equiv).

d

Reaction: diene (0.25 mmol).