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. 2014 Apr 14;136(18):6733–6743. doi: 10.1021/ja5021958

Table 2. Summary of Rate Information for Ruthenium Complexes 4 and 6a.

entry 4 k from 4 (×10–4 s–1)b 4:5:6c k from 6 (×10–3 s–1)b calcddk from 6 (×10–4 s–1)
1 4a 2.7 ± 0.1 69:25:6 1.6 ± 0.1 2.7
2 4b 1.2 ± 0.1 3:38:59 0.084
3 4c 2.0 ± 0.1 56:43:<1 1.7 × 106
4 4d <0.1 >98:<1:<1 1.4 ± 0.2 2.6
a

All data from experiments conducted at 40 °C.

b

Uncertainty reported with 90% confidence intervals.

c

Relative concentrations of complexes at equilibrium.

d

See Supporting Information for details.