Table 2. Lumi-R Quantum Yields (ΦLumi-R) under Each Experimental Condition of Temperature and Excitation Pulse Energya.
Pr 2 occupancy (%) | branching % to Lumi-R | ΦLumi-R (%) | |
---|---|---|---|
temperature dependence (630 nm excitation) | |||
8 °C | 48 | 29 | 14 |
25 °C | 48 | 30 | 14.4 |
40 °C | 40 | 34 | 13.6 |
excitation energy dependence (at 25 °C) | |||
600 nm excitation | 32 | 30 | 9.6 |
670 nm excitation | 40 | 30 | 12 |
The branching ratio is calculated based on τ (Pr 2* → Pr 2) and τ (Pr 2* → Lumi-R) in Figure 5. The ΦLumi-R is calculated by Pr 2 occupancy × branching % to Lumi-R.