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. 2013 Jan 15;257(2):541–563. doi: 10.1016/j.ccr.2012.04.028

Fig. 11.

Fig. 11

Reaction mechanism of CDO involving attack of the proximal oxygen atom at the metal coordinated sulfur atom of the substrate, as proposed based on a crystal-structure which has a persulfenate bound to the Fe(II) center.

Adapted from ref. [51].