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. Author manuscript; available in PMC: 2015 Mar 1.
Published in final edited form as: Green Chem. 2013 Dec 5;16(3):1097–1100. doi: 10.1039/C3GC42119H

Table 4.

Effects of metal salts on the yields of the annulated pyridine 3 and substituted indole 4. a

graphic file with name nihms-547035-t0005.jpg
entry metal 3 4
1 none 73 64
2 ZnCl2b 51 42
3 ZnCl2c 0 0
4 CuI 53 49
5 CuOAc 54 50
6 CuBr-SMe2 52 47
7 NiCl2 42 NDd
8 Nil2(PPh3)2 47 NDd
9 Ni(COD)2 45 NDd
a

Conditions: substrate (0.15 mmol); metal salts (10 mol %) NaSO2CF3 (3 equiv); TBHP (5 equiv); TPGS-750-M:water (2 wt. %),

b

TMEDA (1 equiv),

c

1,10-Phen (1 equiv),

d

Not Determined.