Table 1.
Glass-transition temperature (Tg), melting temperature (Tm), endothermic heat (ΔHf), crystallinity (χc), Fourier transform infrared (FTIR) deconvolution result, Arrhenius activation energy (Ea) and Vogel-Tamman-Fulcher (VTF) parameters of TIE(Y)-Z hybrid electrolytes with various [O]/[Li] ratios.
| Samples | TIE (2000)-Z | TIE (600)-Z | ||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Tg (°C) | Tm (°C) | Δ Hf (J g−1) | χc (%) | Free ClO4−, % (~625 cm−1) | Ea (eV) | A (Scm−1 K 0.5) | B (eV) | Tg (°C) | Free ClO4−, % | |
| Z | ||||||||||
| Pure ED2000 | - | 38.7 | 111.7 | 100 | - | - | - | - | - | - |
| ∞ | - | 25.9 | 56.6 | 50.6 | - | - | - | - | −31.7 | - |
| 32 | −49.8 | 23.5 | 39.9 | 35.5 | 100 | 0.32 | 36.7 | 0.13 | −25.5 | 85.2 |
| 24 | −45.8 | 21.6 | 29.3 | 26.3 | 88.2 | 0.3 | 60.2 | 0.12 | −20.0 | 81.3 |
| 16 | −32.6 | - | - | - | 85.7 | 0.35 | 141.6 | 0.12 | −11.5 | 79.3 |
| 8 | −11.7 | - | - | - | 75 | 0.42 | 60.5 | 0.1 | 7.8 | 73.3 |