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. 2014 May 4;2014:170959. doi: 10.1155/2014/170959

Table 1.

Major chemical constituents identified in crude and processed Paeoniae Radix Alba and in crude and processed Paeoniae Radix Alba-Atractylodis Macrocephalae Rhizoma herbal pair.

No. t R (min) Compound name Formula Paeoniae
Radix Alba		 Paeoniae Radix Alba-Atractylodis Macrocephalae Rhizoma herbal pair
(Measured area) (Measured area)
Crude Processed Crude Processed
1 0.84 6-O-galloylsucrose C19H26O15 1.8570E + 08 1.9012E + 08 4.2870E + 07 4.4158E + 07
2 0.84 Glucogallin C13H16O10 2.9739E + 08 2.5698E + 08 1.0931E + 08 —
3 1.05 Desbenzoylpaeoniflorin C16H24O10 1.6682E + 08 1.6263E + 08 9.8500E + 07 —
4 1.06 1′-O-galloylsucrose C19H26O15 3.2574E + 08 2.9123E + 08 — —
5 1.07 1-O-glucopyranosyl paeonisuffrone C16H24O9 2.8667E + 08 2.3654E + 08 1.1532E + 08 —
6 1.13 Gallic acid C7H6O5 4.1152E + 09 4.0736E + 09 2.7186E + 09 3.1711E + 09
7 1.18 Oxypaeoniflorin sulfonate C23H28O14S 4.9527E + 07 3.5407E + 07 6.1568E + 06 8.5010E + 07
8 1.22 Ethyl gallate C9H10O5 5.1351E + 07 6.7200E + 07 1.5592E + 07 4.8337E + 07
9 1.22 6-O-galloyl desbenzoylpaeoniflorin C23H28O14 9.9020E + 07 9.5040E + 07 5.3798E + 07 —
10 1.26 6-O-glucopyranosyl-lactinolide C16H26O9 1.0875E + 08 1.1180E + 08 — 3.7130E + 07
11 1.30 Paeoniflorin sulfonate I C23H28O13S 5.3777E + 07 3.6391E + 07 7.3077E + 06 7.7185E + 07
12 1.30 Mudanpioside E sulfonate C24H30O15S 5.3777E + 07 3.6391E + 07 7.3077E + 06 7.7185E + 07
13 1.43 6-O-glucopyranosyl-lactinolide C16H26O9 7.4342E + 08 6.5904E + 08 4.0712E + 08 3.1407E + 08
14 1.64 Mudanpioside F C16H24O8 6.4178E + 08 6.0980E + 08 4.0130E + 08 6.6680E + 07
15 1.76 Isomaltopaeoniflorin sulfonate C29H38O18S 1.8858E + 09 1.1382E + 09 2.6277E + 08 5.8622E + 07
16 1.81 Pedunculagin C34H24O22 4.8098E + 07 — 5.6076E + 07 1.2660E + 09
17 1.97 Paeoniflorin sulfonate I C23H28O13S 3.1881E + 10 2.3387E + 10 6.6202E + 09 5.5241E + 10
18 2.25 Oxypaeoniflorin C23H28O12 2.3173E + 09 2.4115E + 09 1.6734E + 09 1.4513E + 09
19 2.36 Gallotannin C27H24O18 2.2850E + 08 2.2458E + 08 1.6284E + 08 1.6703E + 08
20 2.37 1-O-benzoylsucrose C19H26O12 1.3761E + 08 1.3161E + 08 1.1673E + 08 8.2986E + 07
21 2.41 d-catechin C15H14O6 3.7822E + 09 4.2278E + 09 2.6339E + 09 2.5982E + 09
22 2.63 Methyl gallate C8H8O5 2.3823E + 10 2.4116E + 10 2.3388E + 10 —
23 2.63 Salicylic acid C7H6O3 2.3823E + 10 2.4116E + 10 2.3388E + 10 1.7399E + 10
24 2.72 Albiflorin R1 C23H28O11 5.2469E + 08 5.6725E + 08 5.6329E + 08 4.5647E + 08
25 3.00 Kaempferol-3,7-di-O-glucoside C27H30O16 3.8065E + 07 2.1896E + 07 3.5719E + 07 1.5513E + 07
26 3.00 Paeonoside C27H30O16 3.8065E + 07 2.1896E + 07 3.5719E + 07 1.5513E + 07
27 3.46 Galloylpaeoniflorin C30H32O15 1.3912E + 08 1.5200E + 08 1.1501E + 08 1.0863E + 08
28 3.47 Paeonolide C20H28O12 1.0622E + 07 1.1936E + 07 9.1812E + 06 —
29 3.58 6-O-glucopyranosyl-lactinolide C16H26O9 2.5249E + 08 2.3834E + 08 2.2675E + 08 2.1241E + 08
30 3.68 Oxypaeoniflorin C23H28O12 1.5407E + 08 — 1.4345E + 08 1.3307E + 08
31 3.76 6-O-glucopyranosyl-lactinolide C16H26O9 3.2664E + 08 — 3.0588E + 08 3.1627E + 08
32 3.88 Paeonilactone B C10H12O4 9.0325E + 07 9.3539E + 07 5.1257E + 07 8.9597E + 07
33 3.93 Isomaltopaeoniflorin C29H38O16 1.1545E + 10 1.1941E + 10 1.2282E + 10 9.4600E + 09
34 4.07 Albiflorin C23H28O11 2.9587E + 10 2.9296E + 10 2.8430E + 10 2.8684E + 10
35 4.32 Glucopyranosylalbiorin C29H38O16 2.2813E + 09 2.4109E + 08 2.0383E + 08 1.6844E + 08
36 4.34 Galloylpaeoniflorin sulfonate C30H32O17S 7.6943E + 08 5.6793E + 08 1.5501E + 08 1.4886E + 09
37 4.34 Galloylpaeoniflorin isomer C30H32O15 6.7592E + 08 7.4322E + 08 6.0470E + 08 5.4051E + 08
38 4.38 1,2,3,6-tetra-O-galloylglucose C34H28O22 4.6602E + 08 3.4977E + 08 4.0697E + 08 3.6901E + 08
39 4.38 Tetragalloyl glucose A C34H28O22 4.6602E + 08 3.4977E + 08 4.0697E + 08 3.6901E + 08
40 4.56 Mudanpioside F C16H24O8 8.4156E + 07 8.2734E + 07 7.2666E + 07 7.9227E + 07
41 4.60 Oxypaeoniflorin isomer C23H28O12 9.6610E + 08 9.8706E + 08 9.2464E + 08 8.7359E + 08
42 4.65 Gallotannin C27H24O18 6.7737E + 07 — — —
43 4.77 Paeoniflorin C23H28O11 5.9556E + 10 6.1356E + 10 5.9929E + 10 5.8832E + 10
44 4.89 Paeoniflorin sulfonate II C23H28O13S 1.1095E + 08 1.4567E + 08 5.5052E + 07 2.7813E + 08
45 4.98 Isogalloylpaeoniflorin sulfonate C30H32O17S 3.6742E + 07 — — —
46 5.05 Ethyl gallate C9H10O5 6.0669E + 07 5.4850E + 07 1.6681E + 07 2.6790E + 07
47 5.05 Methyl salicylate C8H8O3 6.0669E + 07 5.4850E + 07 1.6681E + 07 2.6790E + 07
48 5.15 Benzoic acid C7H6O2 4.0163E + 07 4.5493E + 07 2.9695E + 07 2.9727E + 07
49 5.25 Paeonol C9H10O3 6.8567E + 07 7.4129E + 07 9.9992E + 07 6.5619E + 07
50 5.25 4-hydroxy-3-methoxy acetophenone C9H10O3 6.8567E + 07 7.4129E + 07 9.9992E + 07 6.5619E + 07
51 5.31 ortho-oxypaeoniflorin C23H28O12 1.9080E + 09 1.9263E + 09 1.8723E + 09 1.6842E + 09
52 5.63 Ethyl gallate C9H10O5 1.4627E + 08 1.2812E + 08 1.0365E + 08 8.8155E + 07
53 5.63 Methyl salicylate C8H8O3 1.4627E + 08 1.2812E + 08 1.0365E + 08 8.8155E + 07
54 5.66 Kaempferol-3-O-glucoside C21H20O11 1.6012E + 07 1.7385E + 07 — —
55 5.66 Astragalin C21H20O11 1.6012E + 07 1.7385E + 07 — —
56 6.01 Eugeniin C41H30O26 2.7483E + 08 3.0279E + 08 2.8080E + 08 3.0479E + 08
57 6.01 Dihydroxymethyl benzoyl tetragalloyl glucose C41H30O26 2.7483E + 08 3.0279E + 08 2.8080E + 08 3.0479E + 08
58 6.03 1,2,3,6-tetra-O-galloylglucose isomer A C34H28O22 1.3555E + 09 — 1.1980E + 09 1.1039E + 09
59 6.03 Tetragalloyl glucose B C34H28O22 1.3555E + 09 — — —
60 6.08 Astragalin C21H20O11 1.5009E + 07 1.8552E + 07 1.5922E + 07 1.4002E + 07
61 6.09 Isomaltopaeoniflorin isomer C29H38O16 7.5172E + 07 — — —
62 6.47 1,2,3,6-tetra-O-galloylglucose isomer B C34H28O22 1.5882E + 09 — — 1.2570E + 09
63 6.47 Tetragalloyl glucose C C34H28O22 1.5882E + 09 — — 1.2570E + 09
64 6.85 3,6-di-O-galloyl paeoniorin C37H36O19 7.6512E + 07 — — —
65 6.96 1,2,3,6-tetra-O-galloylglucose C34H28O22 4.4729E + 08 4.5825E + 08 4.0642E + 08 4.2393E + 08
66 6.96 Tetragalloyl glucose D C34H28O22 4.4729E + 08 4.5825E + 08 4.0642E + 08 4.2393E + 08
67 7.35 Galloylpaeoniflorin isomer I C30H32O15 1.2156E + 10 1.2451E + 10 1.1484E + 10 1.0962E + 10
68 7.60 1-O-glucopyranosyl-8-O-benzoyl paeonisuffrone C23H28O10 4.3983E + 07 4.5347E + 07 4.4927E + 07 3.9869E + 07
69 7.71 Glucopyranosylalbiorin isomer I C29H38O16 7.2982E + 07 7.9341E + 07 — 1.8872E + 07
70 8.18 1-O-glucopyranosyl-8-O-benzoyl paeonisuffrone C23H28O10 7.4648E + 07 8.3204E + 07 6.5957E + 07 5.9832E + 07
71 8.31 Ortho-oxypaeoniflorin C23H28O12 2.4469E + 07 2.4504E + 07 2.3932E + 07 2.2796E + 07
72 8.45 1,2,3,4,6-Penta-O-galloyl–D-glucopyranose C41H32O26 1.1843E + 10 1.0905E + 10 1.0518E + 10 1.0489E + 10
73 8.45 Pentagalloyl glucose C41H32O26 1.1843E + 10 1.0905E + 10 1.0518E + 10 1.0489E + 10
74 8.64 Lactiflorin C23H26O10 1.0818E + 08 1.8628E + 08 1.3689E + 08 —
75 8.80 Galloylalbiroin C30H32O15 3.2696E + 09 — — —
76 9.17 Astragalin C21H20O11 1.0717E + 07 1.3960E + 07 1.2843E + 07 1.0582E + 07
77 9.25 Lactinolide C10H16O4 2.7251E + 07 2.6105E + 07 2.1735E + 07 3.2770E + 07
78 9.29 Galloylpaeoniflorin isomer II C30H32O15 2.8831E + 09 — 2.6829E + 09 2.2850E + 09
79 9.68 Glucopyranosylalbiorin isomer II C29H38O16 2.4321E + 07 2.6804E + 07 2.2576E + 07 2.4950E + 07
80 9.84 Hexagalloyl glucose C48H36O30 4.9153E + 07 — 6.8676E + 08 5.7793E + 08
81 9.95 Oxybenzoyl-oxypaeoniflorin C30H32O14 1.4385E + 07 1.6654E + 07 1.1051E + 07 1.1345E + 07
82 10.07 1-O-glucopyranosyl-8-O-benzoylpaeonisuffrone C23H28O10 3.6916E + 09 3.5634E + 09 3.1333E + 09 3.2106E + 09
83 10.29 Albiflorin R1 isomer I C23H28O11 6.3346E + 09 6.6205E + 09 5.9528E + 09 5.8736E + 09
84 10.74 Hexagalloyl glucose C48H36O30 4.9225E + 08 2.5582E + 08 1.9395E + 09 1.5439E + 09
85 10.76 Lactiflorin C23H26O10 1.2785E + 09 3.5174E + 09 9.9713E + 08 3.4524E + 09
86 10.84 Benzoylpaeoniflorin Sulfonate C30H32O14S 9.0616E + 08 6.4075E + 08 1.5946E + 08 2.1931E + 09
87 10.88 3,6-di-O-galloyl paeoniorin C37H36O19 1.6123E + 08 — — —
88 10.95 Ortho-oxypaeoniflorin isomer C23H28O12 5.5563E + 07 5.8774E + 07 5.7147E + 07 5.6640E + 07
89 11.52 3,6-di-O-galloyl paeoniorin C37H36O19 3.6509E + 08 3.9290E + 08 5.2162E + 08 5.3781E + 08
90 11.72 3,6-di-O-galloyl paeoniorin isomer C37H36O19 9.7356E + 08 — 1.2523E + 09 9.5929E + 08
91 11.75 Galloylalbiroin isomer I C30H32O15 2.3457E + 08 — — —
92 11.84 Oxypaeoniflorin sulfonate isomer C23H28O14S 2.1063E + 07 1.9747E + 07 1.3875E + 07 1.0840E + 07
93 12.15 1-O-glucopyranosyl-8-O-benzoylpaeonisuffrone C23H28O10 7.2104E + 07 7.1468E + 07 6.7309E + 07 6.5917E + 07
94 12.15 Oxybenzoyl-oxypaeoniflorin C30H32O14 1.9982E + 08 — — 1.6891E + 08
95 12.18 Benzoyloxypaeoniflorin C30H32O13 2.0822E + 08 — 2.0163E + 08 1.9074E + 08
96 13.42 Benzoyloxypaeoniflorin isomer C30H32O13 8.6458E + 07 6.2282E + 07 7.6048E + 07 7.2791E + 07
97 13.44 Oxybenzoyl-oxypaeoniflorin isomer I C30H32O14 1.4728E + 07 1.7389E + 07 1.5360E + 07 1.6008E + 07
98 13.85 Galloylalbiroin isomer II C30H32O15 9.6403E + 07 1.2196E + 08 1.0506E + 08 1.0272E + 08
99 14.05 Oxybenzoyl-oxypaeoniflorin isomer II C30H32O14 2.5323E + 07 2.9603E + 07 2.3556E + 07 2.8526E + 07
100 14.13 Benzoyloxypaeoniflorin C30H32O13 3.8096E + 07 3.8557E + 07 3.7499E + 07 3.5800E + 07
101 15.07 Benzoyloxypaeoniflorin isomer I C30H32O13 1.9827E + 07 2.3616E + 07 — —
102 15.38 Benzoyloxypaeoniflorin isomer II C30H32O13 1.1841E + 07 1.3730E + 07 — —
103 16.01 Oxybenzoyl-paeoniflorin C30H32O12 1.8152E + 07 — 1.8435E + 07 —
104 16.95 Isobenzoylpaeoniflorin C30H32O12 1.2225E + 10 1.3228E + 10 1.2158E + 10 1.2391E + 10
105 16.95 Oxybenzoyl-paeoniflorin isomer I C30H32O12 1.2225E + 10 1.3228E + 10 1.2158E + 10 1.2391E + 10
106 17.23 Benzoylpaeoniflorin Sulfonate C30H32O14S 1.5680E + 07 1.2235E + 07 5.6573E + 06 3.5831E + 07
107 17.48 Isobenzoylpaeoniflorin isomer I C30H32O12 5.4138E + 09 5.4432E + 09 5.2522E + 09 5.3238E + 09
108 17.48 Oxybenzoyl-paeoniflorin isomer II C30H32O12 5.4138E + 09 5.4432E + 09 5.2522E + 09 5.3238E + 09
109 17.86 Benzoyloxypaeoniflorin C30H32O13 3.4347E + 07 3.4852E + 07 3.5980E + 07 3.8814E + 07
110 18.55 Benzoyloxypaeoniflorin isomer C30H32O13 1.5397E + 07 1.7656E + 07 1.7246E + 07 1.8012E + 07
111 18.69 Albiflorin R1 isomer II C23H28O11 2.0046E + 07 1.9851E + 07 2.3462E + 07 —
112 19.30 Albiflorin R1 isomer III C23H28O11 2.9827E + 06 — — 5.6105E + 06
113 21.79 Palbinone C22H30O4 8.9687E + 07 1.3174E + 08 1.2834E + 08 5.7610E + 07
114 21.93 Isobenzoylpaeoniflorin isomer II C30H32O12 4.5356E + 08 4.2874E + 07 3.4016E + 08 2.7347E + 08
115 21.93 Oxybenzoyl-paeoniflorin isomer III C30H32O12 4.5356E + 08 4.2874E + 07 3.4016E + 08 2.7347E + 08
116 22.15 Paeonilactinone C10H16O2 7.0423E + 06 3.7108E + 06 8.0036E + 06 6.6886E + 06
117 36.46 Hederagenin C30H48O4 7.6725E + 07 8.1456E + 07 9.7498E + 07 4.7332E + 07
118 37.31 23-hydroxybetulinic acid C30H48O4 3.9836E + 07 4.0995E + 07 3.9906E + 07 2.2611E + 07
119 38.14 Astrantiagenin D C30H46O4 7.8714E + 06 7.9560E + 06 1.1904E + 07 3.8958E + 06
120 43.00 Astrantiagenin D isomer C30H46O4 4.0450E + 06 — 3.1585E + 06 —
121 45.65 Oleanolic acid C30H48O3 1.1266E + 08 9.4258E + 07 7.6434E + 07 4.3295E + 07
122 46.10 Betulinic acid C30H48O3 6.2494E + 06 2.3289E + 07 4.0543E + 07 2.3912E + 07
123 52.48 Daucosterol C35H60O6 1.4060E + 07 1.9624E + 07 8.5440E + 06 6.3156E + 06