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. Author manuscript; available in PMC: 2015 Jun 1.
Published in final edited form as: J Biol Inorg Chem. 2014 Jan 16;19(0):515–528. doi: 10.1007/s00775-013-1081-6

Figure 2.

Figure 2

Displacement ellipsoid plot (50% probability level) of the copper complexes, showing the atom-labeling scheme. Relevant bond lengths (Å) and angles (deg) of a) [(AN)CuII(Cl)]+, Cu-N(1), 2.028 (2); Cu-N(2), 1.998 (2); Cu-N(3), 2.031 (2); Cu-Cl(1), 2.227 (6); N(1)-Cu-N(2), 96.5 (7); N(1)-Cu-N(3), 138.6 (4); N(2)-Cu-N(3), 95.7 (7); N(1)-Cu-C1(1), 102.6 (6); N(2)-Cu-Cl(1), 126.6 (8); N(3)-Cu-C1(1), 101.0 (8) and b) [(AN)CuII(NO2)]+, Cu-N(1), 2.011 (4); Cu-N(2), 1.993 (2); Cu-N(3), 2.043 (2); Cu-O(1), 2.347 (3); Cu-O(2), 2.002 (2); N(1)-Cu-N(2), 97.6 (1); N(1)-Cu-N(3), 136.8 (1); N(2)-Cu-N(3), 94.8 (9); N(1)-Cu-O(1), 109.0 (1); N(1)-Cu-O(2), 92.9 (1); N(2)-Cu-O(1), 95.7 (9); N(2)-Cu-O(2), 152.0 (6); N(3)-Cu-O(1), 110.6 (7); N(3)-Cu-O(2), 95.0 (1); O(1)-Cu-O(2), 56.2 (8).