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. Author manuscript; available in PMC: 2015 Jun 1.

Published in final edited form as: J Biol Inorg Chem. 2014 Jan 16;19(0):515–528. doi: 10.1007/s00775-013-1081-6

a) UV-vis spectra of (F₈)Fe^II (8 µM) (, λ_max = 420 (Soret), 541 nm) and reaction solution of (F₈)Fe^II and [(AN)Cu^II(NO₂)](CF₃SO₃) after stirring for 10 min (15 µM) () and 1 h (15 µM) (, λ_max = 399, 439 (Soret), 558 nm) in acetone at RT. b) EPR spectrum of the products of the reaction of (F₈)Fe^II and [(AN)Cu^II(NO₂)](CF₃SO₃) in acetone at 20 K (2mM).

Inline graphic — a) UV-vis spectra of (F₈)Fe^II (8 µM) (, λ_max = 420 (Soret), 541 nm) and reaction solution of (F₈)Fe^II and [(AN)Cu^II(NO₂)](CF₃SO₃) after stirring for 10 min (15 µM) () and 1 h (15 µM) (, λ_max = 399, 439 (Soret), 558 nm) in acetone at RT. b) EPR spectrum of the products of the reaction of (F₈)Fe^II and [(AN)Cu^II(NO₂)](CF₃SO₃) in acetone at 20 K (2mM).