Table 2. Catalytic Homoallylation Scope^a.

^aReagents 2 and 3 were used in racemic form.

^bAll reactions were performed with 3.0 equiv f boronates 1–3, except where indicated. Entries 3–8 are reactions run at 45 °C, and all others were run at rt.

^cIsolated yields for reactions on 0.1–0.3 mmol scale, except where indicated. For volatile substrates, NMR yields are listed in parentheses. The diastereomeric ratios, as determined by ¹H NMR integration, were >20:1 for 6a–k and >12:1 for 7a–k.

^dIsolated yield for reaction run on 1 mmol scale and with 2.0 equiv of 1.