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. 2014 May 9;33(10):2489–2495. doi: 10.1021/om401226j

Table 3. Apparent Rate Constants (kobs) for the Polymerization of rac-Lactidea.

entry cat. kobs (h–1) entry cat. kobs (h–1)
1 2a 0.248 (±0.009) 5 2g 0.173 (±0.006)
2 2c 0.11 (±0.04) 6 2h 0.21 (±0.04)
3b 2c 0.09 (±0.02) 7 2i 0.17 (±0.06)
4 2e 0.16 (±0.01)      
a

The kinetic experiments were run in the presence of 1 equiv of BnOH (vs Al catalysts); see Experimental section for details.

b

l-Lactide was used.