Table 3. Apparent Rate Constants (kobs) for the Polymerization of rac-Lactidea.
| entry | cat. | kobs (h–1) | entry | cat. | kobs (h–1) |
|---|---|---|---|---|---|
| 1 | 2a | 0.248 (±0.009) | 5 | 2g | 0.173 (±0.006) |
| 2 | 2c | 0.11 (±0.04) | 6 | 2h | 0.21 (±0.04) |
| 3b | 2c | 0.09 (±0.02) | 7 | 2i | 0.17 (±0.06) |
| 4 | 2e | 0.16 (±0.01) |
The kinetic experiments were run in the presence of 1 equiv of BnOH (vs Al catalysts); see Experimental section for details.
l-Lactide was used.