Table II.
Physical Characterization of Emulsions Containing Salicylic Acid Presented as Average ± SD
| Whey | Chi | Car | |||||||
|---|---|---|---|---|---|---|---|---|---|
| pH 4 | pH 5 | pH 6 | pH 4 | pH 5 | pH 6 | pH 4 | pH 5 | pH 6 | |
| Zeta potentiala (mV) | |||||||||
| With Sal | 23.9 ± 0.8 | 3.8 ± 1.8 | −8.6 ± 1.4 | 32.4 ± 2.0 | 21.6 ± 0.8 | 14.9 ± 3.6 | 15.5 ± 0.8 | −13.0 ± 1.2 | −32.5 ± 12.2 |
| Without Sal | 23.7 ± 0.5 | 6.4 ± 2.2 | −9.7 ± 0.6 | 26.7 ± 1.3 | 20.7 ± 1.5 | 9.5 ± 3.1 | 22.5 ± 0.3 | −18.7 ± 5.5 | −21.0 ± 2.1 |
| Particle sizeb (μm) | |||||||||
| Day 0 | |||||||||
| D [4,3] | 2.61 ± 0.09 | 2.85 ± 0.06 | 2.47 ± 0.01 | 25.77 ± 3.21 | 46.07 ± 1.28 | 38.34 ± 3.01 | 3.09 ± 0.03 | 2.54 ± 0.02 | 2.39 ± 0.06 |
| D [3,2] | 1.85 ± 0.02 | 2.08 ± 0.02 | 1.80 ± 0.01 | 5.19 ± 0.41 | 5.84 ± 0.08 | 14.37 ± 0.83 | 2.31 ± 0.03 | 1.99 ± 0.02 | 1.90 ± 0.06 |
| Day 1 | |||||||||
| D [4,3] | 3.63 ± 1.12 | 94.13 ± 2.87 | 2.50 ± 0.03 | 46.77 ± 4.47 | 70.69 ± 7.32 | 36.36 ± 0.68 | 9.09 ± 4.92 | 16.22 ± 12.1 | 7.71 ± 6.18 |
| D [3,2] | 1.82 ± 0.02 | 21.68 ± 1.01 | 1.82 ± 0.02 | 7.66 ± 0.13 | 11.45 ± 0.08 | 13.76 ± 0.20 | 2.50 ± 0.09 | 2.12 ± 0.12 | 2.07 ± 0.13 |
| Day 7 | |||||||||
| D [4,3] | 3.69 ± 1.21 | 93.64 ± 6.71 | 2.38 ± 0.03 | 47.23 ± 4.85 | 58.02 ± 3.00 | 37.25 ± 1.57 | 7.64 ± 4.95 | 2.69 ± 0.04 | 2.26 ± 0.01 |
| D [3,2] | 1.83 ± 0.04 | 18.02 ± 2.92 | 1.79 ± 0.02 | 7.61 ± 0.19 | 10.60 ± 0.36 | 13.69 ± 0.30 | 2.46 ± 0.10 | 1.99 ± 0.01 | 1.74 ± 0.01 |
| CIc (%) | 0 | 47.3 | 0 | 57.1 | Flocs | 0 | 73.2 | 83.9 | 91.1 |
| Viscosityd (mPa s) | 7.88 ± 0.03 | 19.24 ± 0.71 | 4.69 ± 0.04 | 17.16 ± 0.09 | 5.99 ± 0.02 | 13.92 ± 0.08 | 13.65 ± 0.03 | 13.31 ± 0.09 | 10.18 ± 0.06 |
Whey whey protein, Chi whey protein/chitosan, Car whey protein/carrageenan, Sal salicylic acid, D[4,3] volume weighted mean diameter and D[3,2] surface weighted mean diameter, CI creaming index
a n = 3
b n = 4
cDetermined after 7 days
d n = 10