Table 1. NMR Data of Compound 1a and 1b in CD3CN-d3.
1a |
1b |
|||
---|---|---|---|---|
no. | δC | δH (J in Hz) | δC | δH (J in Hz) |
1 | NDa | ND | ||
2 | 108.2 C | 108.0 C | ||
3 | 161.1 C | ND | ||
4 | 120.7 C | 121.1 C | ||
5 | 150.1 C | ND | ||
6 | 120.9 CH | 7.42 brs | ND | 7.28 brs |
7 | 139.2 C | |||
8 | 57.7 CH | 4.37 s | 57.5 CH | 4.46 s |
9 | 145.4 C | ND | ||
10 | 109.7 CH | 6.00 brs | 109.2 CH | 6.35 brs |
11 | 164.2 CH | ND | ||
12 | 102.7 CH | 6.22 s | 102.6 CH | 6.15 s |
13 | 165.2 C | 165.3 C | ||
14 | 111.3 C | 112.4 C | ||
15 | 192.0 C | ND | ||
16 | 116.4 C | 115.1 C | ||
17 | 158.1 C | 158.6 C | ||
18 | 125.1 C | 125.2 C | ||
19 | 20.2 CH2 | 2.76 m; 2.33 m | 20.4 CH2 | 2.83 m; 2.50 m |
20 | 31.2 CH2 | 2.74 m | 30.7 CH2 | 2.73 m |
21 | ND | ND | ||
22 | 120.4 CH | 6.75 s | 120.2 CH | 6.74 s |
23 | 140.1 C | ND | ||
24 | ND | 3.27 brs | ND | 3.23 brs |
25 | ND | ND | ||
26 | 28.5 CH3 | 1.76 s | 28.2 CH3 | 1.75 s |
17-OH | 11.87 s | 12.10 s | ||
13-OH | 11.94 s | 11.80 brs | ||
1-COOH | 12.16 brs | 12.3 brs |
ND: not detected.