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. Author manuscript; available in PMC: 2015 Jun 1.
Published in final edited form as: J Biol Inorg Chem. 2014 Mar 11;19(0):491–504. doi: 10.1007/s00775-014-1122-9

Fig. 9.

Fig. 9

Calculated structures for the initially formed (catH)Fe(III)-superoxo adduct (left), the Fe(II)-alkylperoxoH intermediate that affords ring cleavage (middle), and the dead-end [Fe(III)(semiquinone)OOH] byproduct (right) [54].