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. Author manuscript; available in PMC: 2015 Apr 9.
Published in final edited form as: Chem Rev. 2014 Mar 3;114(7):3659–3853. doi: 10.1021/cr400327t

Figure 100.

Figure 100

Diagram (middle) showing the transition between end-on and side-on with frontier molecular orbitals of [TMG3trenCuO2]+ as the end-on example and the frontier molecular orbital of tris-pyrazolyl borate Cu(II)-superoxo as the side-on example.