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. Author manuscript; available in PMC: 2015 Apr 9.
Published in final edited form as: Chem Rev. 2014 Mar 3;114(7):3659–3853. doi: 10.1021/cr400327t

Figure 172.

Figure 172

2 Dimentional energy surface plots of proton assisted- and unassisted pathways, as well as intermediate pathways with concurrent elongation of the O-O bond and formation of the μ2-O-H bond. Proton unassisted pathway goes through TS1 and proton assisted pathway through TS2. (Reprinted with permission from Ref. 906. Copyright 2007 American Chemical Society.)