Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Schematic of the spin topology of the reductive cleavage of a putative peroxointeremdaite in CcO to generate PM. A spin down electron originates from the Fe, and a spin up electron originates from the crosslinked tyrosine to fill the σ* of the peroxide ligand. (Reprinted with permission from Ref. 1075. Copyright 2011 American Chemical Society).
