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. Author manuscript; available in PMC: 2015 Apr 9.
Published in final edited form as: Chem Rev. 2014 Mar 3;114(7):3659–3853. doi: 10.1021/cr400327t

Figure 29.

Figure 29

A. Active site of Plastocyanin, showing the short Cu-S bond (equatorial) and the long Cu-S bond from the thioether (axial). B. Ground state wavefunction (β-LUMO) of a blue Cu site.