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. Author manuscript; available in PMC: 2015 Apr 9.

Published in final edited form as: Chem Rev. 2014 Mar 3;114(7):3659–3853. doi: 10.1021/cr400327t

Spectral changes observed upon addition of azide to nitrite bound half-met-Hc results in significant spectral changes. A. UV-Vis absorption of NO₂⁻ bound half-met-Hc () and N₃⁻ bound half-met-Hc (); B: EPR spectra of NO₂⁻ bound half-met-Hc () and N₃⁻ bound half-met-Hc ().

Inline graphic — Spectral changes observed upon addition of azide to nitrite bound half-met-Hc results in significant spectral changes. A. UV-Vis absorption of NO₂⁻ bound half-met-Hc () and N₃⁻ bound half-met-Hc (); B: EPR spectra of NO₂⁻ bound half-met-Hc () and N₃⁻ bound half-met-Hc ().