Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Schematic molecular orbital diagram of the copper-superoxo bonding in [TMG3trenCuO2]+. The LMCT (red) and IL (blue) transitions are shown, as are the orbital energy separations (Δ). The π*σ (+dz2) MO is dominantly superoxo-based and σ-bonding to dz2 and the dz2(−π*σ) MO is dominantly copper-based and σ-antibonding to π*σ. (Reprinted with permission from ref 123 Copyright 2010 American Chemical Society.))
