Skip to main content
. Author manuscript; available in PMC: 2015 Apr 9.
Published in final edited form as: Chem Rev. 2014 Mar 3;114(7):3659–3853. doi: 10.1021/cr400327t

Table 37.

Representative kinetic parameters for the stoichiometric reduction of various flavonolate model complexes with O2

Conditions k2 (M−1 s−1) ΔH‡
kcal/mol		 ΔS‡
cal/mol•K		 Ref.
potassium flavonolate 80°C, DMF 0.33±0.01 6.9±0.5 −38±1 1128
ZnII(idpa)(fla)ClO4 100°C, DMF (3.1±0.1)×10−3 18±1 −23±3 1131
CuI(PPh3)2(fla) 90°C, DMF (4.2±0.5)×10−3 24 −3 1136
CuII(idpa)(fla)ClO4 100°C, DMF (6.1±0.2)×10−3 15±1 −29±4 1133