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. Author manuscript; available in PMC: 2015 Apr 9.
Published in final edited form as: Chem Rev. 2014 Mar 3;114(7):3659–3853. doi: 10.1021/cr400327t

Table 44.

Bond lengths and angles for CuZ* for aerobically crystallized PdN2OR1327 and CuZ from anaerobically crystallized PsN2OR.1296

CuZ*
PdN2OR1292 		CuZ
PsN2OR1296
Resolution 1.6 Å 1.7 Å
Bond Lengths (Å) (Å)
CuI-CuIV 3.40 3.6
CuI-CuIII 3.39 3.0
CuII-CuIV 2.58 2.9
CuII-CuIII 2.58 2.6
CuIII-CuIV 3.04 3.4
CuI-S1 2.30 2.4
CuII-S1 2.24 1.9
CuIII-S1 2.28 2.1
CuIV-S1 2.36 2.4
CuI-O 2.62 -
CuIV-O 2.80 -
CuI-S2 - 2.5
CuIV-S2 - 2.3