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. Author manuscript; available in PMC: 2014 Jun 9.
Published in final edited form as: Angew Chem Int Ed Engl. 2014 Jan 29;53(7):1910–1914. doi: 10.1002/anie.201309456

Scheme 2.

Scheme 2

Proof-of-principle: Effective combination of three catalytic processes, culminating in the formation of a product containing an all-carbon-substituted quaternary stereogenic center in high enantiomeric purity in less than a total of four hours.