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. Author manuscript; available in PMC: 2015 Jul 1.
Published in final edited form as: J Inorg Biochem. 2014 Jan 10;0:154–160. doi: 10.1016/j.jinorgbio.2013.12.013

Scheme 2.

Scheme 2

Synthetic routes for A) the covalent attachment of the complexes 1–4 to the various single cysteine residues of P450 BM3 heme domain mutants and B) the fully aromatized model compound 2a.