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. Author manuscript; available in PMC: 2015 May 7.
Published in final edited form as: Chem Soc Rev. 2014 Mar 24;43(9):2927–2940. doi: 10.1039/c4cs00054d

Table 21.

Enantioselective allene-olefin [3+2] annulation reported by Miller

graphic file with name nihms582344t21.jpg
entry substrate product() yield +(%) α : ee(%)
1 graphic file with name nihms582344t22.jpg graphic file with name nihms582344t23.jpg 95 > 99 : 1 80
2 graphic file with name nihms582344t24.jpg graphic file with name nihms582344t25.jpg 95 > 99:1 84
3 graphic file with name nihms582344t26.jpg graphic file with name nihms582344t27.jpg 68 94 : 6 65
4 graphic file with name nihms582344t28.jpg graphic file with name nihms582344t29.jpg 75 > 99 : 1 76
5 graphic file with name nihms582344t30.jpg graphic file with name nihms582344t31.jpg 53 > 99 : 1 71