Table 21.
Enantioselective allene-olefin [3+2] annulation reported by Miller
![]() | |||||
|---|---|---|---|---|---|
| entry | substrate | product() | yield +(%) | α : | ee(%) |
| 1 | ![]() |
![]() |
95 | > 99 : 1 | 80 |
| 2 | ![]() |
![]() |
95 | > 99:1 | 84 |
| 3 | ![]() |
![]() |
68 | 94 : 6 | 65 |
| 4 | ![]() |
![]() |
75 | > 99 : 1 | 76 |
| 5 | ![]() |
![]() |
53 | > 99 : 1 | 71 |
Enantioselective allene-olefin [3+2] annulation reported by Miller
![]() | |||||
|---|---|---|---|---|---|
| entry | substrate | product() | yield +(%) | α : | ee(%) |
| 1 | ![]() |
![]() |
95 | > 99 : 1 | 80 |
| 2 | ![]() |
![]() |
95 | > 99:1 | 84 |
| 3 | ![]() |
![]() |
68 | 94 : 6 | 65 |
| 4 | ![]() |
![]() |
75 | > 99 : 1 | 76 |
| 5 | ![]() |
![]() |
53 | > 99 : 1 | 71 |