Table 2.
Metal ion | Cint/CRu | Ru retention efficiency, % | Ru elution efficiency, % | Recovery,% |
---|---|---|---|---|
Ru(III) | – | 93.4 ± 1.5 | 89.7 ± 0.7 | 83.8 ± 1.6 |
Pd(II) | 1 | 91.2 ± 1.3 | 91.6 ± 2.1 | 83.6 ± 2.1 |
10 | 86.9 ± 3.2 | 91.3 ± 2.3 | 79.3 ± 4.8 | |
Pt(IV) | 1 | 87.8 ± 2.0 | 91.2 ± 0.9 | 80.1 ± 1.3 |
5 | 91.5 ± 2.2 | 91.3 ± 2.3 | 83.6 ± 4.1 | |
10 | 74.7 ± 3.2 | 94.8 ± 1.9 | 72.7 ± 1.3 | |
Rh(III) | 1 | 92.7 ± 3.5 | 89.9 ± 1.4 | 83.3 ± 2.1 |
10 | 83.2 ± 1.9 | 91.4 ± 3.0 | 76.0 ± 3.3 | |
Co(II) | 1 | 94.5 ± 2.9 | 90.9 ± 2.9 | 85.9 ± 1.0 |
10 | 93.1 ± 3.7 | 94.3 ± 1.7 | 87.6 ± 3.0 | |
Ni(II) | 1 | 96.7 ± 4.2 | 91.7 ± 3.9 | 88.7 ± 6.4 |
10 | 83.5 ± 1.8 | 98.5 ± 4.7 | 82.2 ± 2.3 | |
Fe(III) | 1 | 96.6 ± 1.8 | 84.6 ± 1.9 | 81.8 ± 2.8 |
10 | 97.7 ± 0.4 | 48.9 ± 4.6 | 47.8 ± 4.5 | |
10 | 97.8 ± 2.1 | 68.3 ± 1.9 | 66.8 ± 1.5a | |
10 | 95.2 ± 1.1 | 77.6 ± 6.6 | 76.9 ± 0.6b | |
10 | 94.4 ± 0.8 | 79.8 ± 2.4 | 75.4 ± 2.8c |
a Column clean-up with 4 mL of 0.05 mol L−1 CH3COOH,
b Sample pH 3.5,
c Sample pH 3.5 and column clean-up with 4 mL of 0.05 mol L−1 CH3COOH.