. Author manuscript; available in PMC: 2014 Jun 24.

Published in final edited form as: Free Radic Res. 2014 Feb 24;48(4):487–502. doi: 10.3109/10715762.2014.886775

Table I.

Correlation between the rate constants, the Cleland coefficients, and the Dalziel coefficients.

Cleland coefficients (k_1r ≠ 0)			Dalziel coefficients (k_1r ≠ 0)
Parameter	Definition	(k_1r ≈ 0)	Parameter	Definition	(k_1r ≈ 0)
V_f	k _4f		Φ ₀	$\frac{1}{k_{4 f}}$
V_r	$\frac{k_{1 r p} k_{2 r p} k_{3 r}}{(k_{1 r p} k_{2 r p} + k_{1 r p} k_{3 r} + k_{2 r p} k_{3 r})}$	≈0	Φ ₁	$\frac{1}{k_{1 f}}$
K_mA	$\frac{k_{1 r p}}{k_{1 f}}$	≈0	Φ ₂	$\frac{1}{k_{2 f p}} + \frac{1}{k_{3 f p}} + \frac{k_{3 r}}{(k_{3 f p} k_{4 f})}$
K _mA1	$\frac{k_{1 r p} k_{3 f p} k_{4 f}}{k_{1 f} (k_{2 f p} k_{4 f} + k_{3 f p} k_{4 f} + k_{2 f p} k_{3 r})}$	≈0	Φ ₁₂	$\frac{k_{1 r p}}{(k_{1 f} k_{2 f p})}$	≈0
K _mA2	$\frac{k_{4 f}}{k_{1 f}}$		Φ ₂₂	$\frac{k_{2 r p} (k_{4 f} + k_{3 r})}{(k_{2 f p} k_{3 f p} k_{4 f})}$
K _mB1	$\frac{k_{2 r p} (k_{4 f} + k_{3 r})}{(k_{2 f p} k_{4 f} + k_{3 f p} k_{4 f} + k_{2 f p} k_{3 r})}$		Φ ₁₂₂	$\frac{k_{1 r p} k_{2 r p} (k_{4 f} + k_{3 r})}{(k_{1 f} k_{2 f p} k_{3 f p} k_{4 f})}$	≈0
K _mB2	$\frac{(k_{2 f p} k_{4 f} + k_{3 f p} k_{4 f} + k_{2 f p} k_{3 r})}{k_{2 f p} k_{3 f p}}$
K _iB1	$\frac{(k_{1 r p} k_{2 r p} + k_{1 r p} k_{3 r} + k_{2 r p} k_{3 r})}{(k_{1 r p} k_{3 f p} + k_{2 f p} k_{3 r})}$
K _iB2	$\frac{(k_{1 r p} k_{3 f p} + k_{2 f p} k_{3 r})}{k_{2 f p} k_{3 f p}}$
K _mP	$\frac{k_{1 r p} k_{2 r p} (k_{4 f} + k_{3 r})}{k_{4 r} (k_{1 r p} k_{2 r p} + k_{1 r p} k_{3 r} + k_{2 r p} k_{3 r})}$	≈0

k_1rp= k_1r f_1r (H); k_2rp=k_2r f_2r (H); k_2fp=k_2f f₂ (H); k_3fp=k_3f f₃ (H).