Table III.

Cleland and Dalziel coefficients calculated from the estimated rate constants for different experimental datasets.

Parameter	Flohé et al. [26] (H2O2) pH = 6.7 (7.7)*	Günzler et al. [34]			Forstrom et al. [36]
		(EthOOH) pH = 6.7 (7.7)	(CumOOH) pH = 6.7 (7.7)	(tBuOOH) pH = 6.7 (7.7)	(CumOOH) pH = 7.2 (7.7)	(LinOOH) pH = 7.2 (7.7)
Cleland coefficients
Vf (s−1)a	7.5 × 104	7.5 × 104	7.5 × 104	7.5 × 104	7.5 × 104	7.5 × 104
KmA3 (M)a	1.1 × 10−3	2 × 10−3	4.9 × 10−3	1.2 × 10−2	1.3 × 10−2	3.5 × 10−3
KmB2 (M)	0.15 (0.017)*	0.17 (0.018)*	0.17 (0.018)*	0.17 (0.018)*	0.49 (0.16)*	0.45 (0.15)*
Dalziel coefficients
Φ0 (s)a	1.3 × 10−5	1.32 × 10−5	1.32 × 10−5	1.32 × 10−5	1.32 × 10−5	1.32 × 10−5
Φ1 (M.s)a	1.4 × 10−8	2.6 × 10−8	6.5 × 10−8	1.6 × 10−7	1.8 × 10−7	4.7 × 10−8
Φ2 (M. s)	2.0 × 10−6 (2.2 × 10−7)*	2.2 × 10−6 (2.4 × 10−7)*	2.3 × 10−6 (2.4 × 10−7)*	2.2 × 10−6 (2.4 × 10−7)*	6.5 × 10−6 (2.1 × 10−6)*	6 × 10−6 (2 × 10−6)*

The K_m values reported here are the Cleland coefficients as defined in Equation (4) and they may not be equivalent to the experimentally derived apparent Michaelis–Menten constants.

^*Values in the parentheses represent for pH 7.7.

^aIndependent of pH. The values of the Cleland and Dalziel coefficients not mentioned in the table are estimated to be zero.