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Effect of copper coordination on the molecular conformation of bis(thiosemicarbazone) ligands. Shown are van der Waals surface representations of GTSM (A) and CuIIGTSM (B). (C) Overlay and alignment of the surface models of CuIIATSM (back) and CuIIGTSM (front). The area of misalignment is magnified in the box to the right. Yellow, blue, gray, and red indicate sulfur, nitrogen, carbon, and copper atoms, respectively. Hydrogen atoms are not shown.
