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. 2014 May 23;5(7):2899–2905. doi: 10.1039/c4sc00950a

Table 3. Revised association constants for 1 from previously obtained data using receptors 2 and 3 as model systems.

Anions Macroscopic association constants
K 11 (M–1) a K 11( Z / S ) (M–1) b , d K 12 (M–1) c , d
Cl (2.30 ± 0.06) × 102 8.0 × 101 1.59 × 103
Br (1.50 ± 0.06) × 102 1.00 × 102 1.59 × 103
HSO4 (3.70 ± 0.06) × 102 2.00 × 102 1.00 × 104
OAc (2.11 ± 0.002) × 104 4.60 × 103 5.25 × 106

aValues determined from re-fitting of titration data to a stepwise 1 : 2 host/guest model with the K 12 value held constant.

bValues calculated from expected statistically corrected equilibrium relationship (K ( Z / S ) = 2K m).

cValues calculated from expected statistically corrected equilibrium relationship (K 12 = αK m 2) and assumed α = 1.

dValues for K m were assumed to be equal to the determined association constant for 3 with the corresponding anion.