Table 3. Revised association constants for 1 from previously obtained data using receptors 2 and 3 as model systems.
Anions | Macroscopic association constants |
||
K 11 (M–1) a | K 11( Z / S ) (M–1) b , d | K 12 (M–1) c , d | |
Cl– | (2.30 ± 0.06) × 102 | 8.0 × 101 | 1.59 × 103 |
Br– | (1.50 ± 0.06) × 102 | 1.00 × 102 | 1.59 × 103 |
HSO4 – | (3.70 ± 0.06) × 102 | 2.00 × 102 | 1.00 × 104 |
OAc– | (2.11 ± 0.002) × 104 | 4.60 × 103 | 5.25 × 106 |
aValues determined from re-fitting of titration data to a stepwise 1 : 2 host/guest model with the K 12 value held constant.
bValues calculated from expected statistically corrected equilibrium relationship (K ( Z / S ) = 2K m).
cValues calculated from expected statistically corrected equilibrium relationship (K 12 = αK m 2) and assumed α = 1.
dValues for K m were assumed to be equal to the determined association constant for 3 with the corresponding anion.