Table 1.
Position | Miconioside C (1) | ||||
---|---|---|---|---|---|
| |||||
δ c | δ h | δ c | δ h | ||
Aglycone | Glc | ||||
2 | 80.2 | 5.47 dd (3.0, 12.9) | 1″ | 105.3 | 4.69 d (7.7) |
3 | 44.5 | 2.85 dd (3.0, 17.0) 3.15 dd (12.9, 17.0) |
2″ | 75.7 | 3.51 t br (8.7) |
4 | 199.5 | 3″ | 78.0 | 3.41 t (8.5) | |
5 | 159.9 | 4″ | 71.7 | 3.25-3.35* | |
6 | 113.2 | 5″ | 77.1 | 3.25-3.35* | |
7 | 162.7 | 6″ | 68.6 | 3.60 dd (5.6, 11.2) 3.84 dd (1.7, 11.2) |
|
8 | 112.0 | Api | |||
9 | 159.0 | 1‴ | 110.9 | 4.89 d (2.0) | |
10 | 106.4 | 2‴ | 77.9 | 3.80 d (2.0) | |
1′ | 140.6 | 3‴ | 80.5 | ||
2′, 6′ | 127.2 | 7.53 d (7.2) | 4‴ | 74.9 | 3.67 d (9.6) 3.74 d (9.6) |
3′, 5′ | 129.7 | 7.42 t (7.2) | 5‴ | 65.9 | 3.49 d (3.1) |
4' | 129.5 | 7.35 t (7.2) | |||
6-Me | 9.8 | 2.14 s br | |||
8-Me | 9.2 | 2.14 s br |
overlapped signals.