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. Author manuscript; available in PMC: 2014 Jun 30.
Published in final edited form as: J Am Chem Soc. 2011 Oct 19;133(44):17786–17795. doi: 10.1021/ja206876h
Y-OH•+ + e ⇔ Y-OH Y-OH•+/Y-OH
Y-O + e + H+ ⇔ Y-OH Y-O•/Y-OH
Y-O + e ⇔ Y-O Y-O•/Y-O
Y-OH•+⇔ Y-O + H+ KoY = [Y-O][H+]/[Y-OH•+]
Y-OH ⇔ Y-O + H+ KrY = [Y-O][H+]/[Y-OH]