Table 2. Selected bond lengths (Å) and angles (°) for complex 8.
Bond lengths | Bond angles | ||
Ni1—O1 | 1.8510(12) | O1—Ni1—N1 | 94.93(6) |
Ni1—N1 | 1.8961(14) | O1—Ni1—S1 | 173.72(4) |
Ni1—P1 | 2.2059(5) | N1—Ni1—S1 | 87.03(4) |
Ni1—S1 | 2.1488(5) | O1—Ni1—P1 | 88.61(4) |
S1—C8 | 1.7529(18) | N1—Ni1—P1 | 171.55(4) |
P1—C17 | 1.8176(17) | S1—Ni1—P1 | 90.261(18) |
P1—C11 | 1.8264(18) | C8—S1—Ni1 | 95.92(6) |
P1—C23 | 1.8249(17) | C7—N1—N2 | 112.62(14) |
O1—C2 | 1.321(2) | C7—N1—Ni1 | 125.76(12) |
O2—C3 | 1.368(2) | N3—C8—S1 | 118.33(13) |
O2—H1 | 0.8400 | N2—C8—S1 | 123.33(13) |
N1—C7 | 1.297(2) | N2— C8— N3 | 118.32(16) |
N1—N2 | 1.400(2) | C17— P1 —Ni1 | 114.97(6) |
N2—C8 | 1.299(2) | C11 —P1 —Ni1 | 114.64(6) |
N3—C8 | 1.359(2) | C23 —P1— Ni1 | 112.34(6) |