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. 2014 May 15;10:1129–1134. doi: 10.3762/bjoc.10.112

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Copyright © 2014, Mikula et al.

This is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)

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Scheme 2 — (A) Regioselective acetylation of resorcylic acid ester 9. (B) Lewis acid mediated glucosylation; no conversion of 10, partially rearrangement of 11 to glucosyl acetamide 12. (C) Königs–Knorr glucosylation; Ag(I): Ag₂CO₃ or Ag₂O, CH₂Cl₂ or MeCN; PTG: phase transfer glucosylation, NaOH, tetrabutylammonium bromide, pH 10–11, CHCl₃/H₂O.