Figure 3.
Bond distances that were used for mapping of relative free energies in the vicinity of the TS plateau for reaction 3. The labels A, S, D, P, and C denote, respectively, associative, synchronous, dissociative reaction pathways, a slice orthogonal to the reaction coordinate, and points belonging to two or more pathways. The A7, S7, D9, and D6 points were used in our analysis of the β–γ substituent effects.