TABLE 3.

Copper structures with similar coordination as EfCBM33A after being subjected to radiation

Copper structures with similar coordination as EfCBM33A after being subjected to radiation, using the criterion described in the text as listed in CSD by their code, oxidation state, bond lengths, maximum N–Cu–N bond angle deviation (from 120°), maximum Cu–N–N–N torsion angle, and assigned configuration. All structures include three-coordinate copper(I) ions. One structures has nearly identical configuration to the irradiated form of EfCBM33A (4ALT): PIVNOX (Tsh, uneven bond distribution), whereas GUVLUF also has the same general layout (highlighted in peach). trig, trigonal; tpy, trigonal pyramidal; Tsh, T-shaped. pt1 and pt2 denote part 1 and part 2 of the same reported structure, denoting crystallographically independent atoms. The 4ALT structural details are included for reference at the end of the table (highlighted in turquoise).