Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Enantioselective C–H oxidation approach to the core furan precursor (−)-22 of the goniothalesdiol family. aSAD = Sharpless Asymmetric Dihydroxylation. Conditions: K2OsO4-2H2O (1 mol%), (DHQD)2PHAL (5 mol%), K2CO3 (3 equiv.), NaHCO3 (3 equiv.) K3Fe(CN)6 (3 equiv.), MeSO2NH2 (1 equiv.), t-BuOH:H2O:CH2Cl2 10:10:1, 0°C-> rt
