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. 2014 Jun 12;4(2):257–274. doi: 10.3390/membranes4020257

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© 2014 by the authors; licensee MDPI, Basel, Switzerland.

This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).

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The interface between AgCl coat at the Ag wire end and KCl solution. s represents the adsorption site on the AgCl surface. Some chloride ions are in the adsorbed state on the AgCl surface. Coordinate system is set as illustrated, where x = 0 represents the interface plane between the AgCl surface and KCl solution phase and x = d represents the plane of ion diffuse phase closest to the adsorption site of AgCl. V represents the potential, where V = 0 at x = ∞. Dotted line represents the potential behavior expected.