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Rotational diffusion rates (kr) determined by EPR spectral simulations, and water diffusion rates (D) determined by DNP, of spin labeled poly(aspartic acid) (PAsp-SL) and PAsp-SL/mfp151 complex coacervates.
| kr (MHz) | D (× 10−9 m2 sec−1) | |
|---|---|---|
|
| ||
| PAsp-SL | 380 (100 %) | 0.63 |
|
| ||
| PAsp-SL / mfp151 Initial[a] |
30.0 (72%) 403 (28%) |
0.69 |
|
| ||
| PAsp-SL / mfp151 Equilibrium (2 d) |
540 (100%) | 1.02 |
|
| ||
EPR spectral simulation returned a two component fit
