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. 2014 Jun 10;136(25):8911–8914. doi: 10.1021/ja504625m

Table 2. Regio-, Diastereo-, and Enantioselective Iridium Catalyzed tert-(Hydroxy)-Prenylation of Alcohols 1a–1i with Isoprene Oxide 3aa.

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a

Yields are of material isolated by silica gel chromatography.

b

THF (1.0 M).

c

3a (400 mol %).

d

THF (0.33 M).

e

60 °C. See Supporting Information for further details.