Table 5. Molecular Parameters for Gd(4b) Bound to HSA Derived from the Simultaneous Fitting of Variable-Temperature NMRD.
τR (ns)a | τv (ps)a | Δ2 (s2) | 310τM (ns) | ΔH⧧ (kJ mol–1) | 310q | ΔH° (kJ mol–1) | |
---|---|---|---|---|---|---|---|
Gd(4b) | 30 | 20 | (4 ± 1) × 1018 | 2.4 ± 0.9 | 28 ± 5 | 0.15 ± 0.02 | 16.8 ± 2.5 |
The parameter was fixed at this value.