Table 1.
wt % PEI | (RNH2/RCHO)a,b | tGel (s) | G’ (Pa) | Maximum Adhesive Stress (kPa) |
---|---|---|---|---|
3.5 | 1.9 (1.8) | 19 | 640 ± 130 | 2.43 ± 0.91 |
5.2 | 2.7 (2.7) | 9 | 1140 ± 250 | 1.83 ± 0.70 |
6.9 | 3.6 (3.6) | 7 | 1740 ± 430 | 2.76 ± 0.48 |
10.3 | 5.4 (5.3) | 3 | 4350 ± 320 | 2.08 ± 0.21 |
RNH2/RCHO ratio calculated by colorimetric analysis and NMR in parenthesis.
PDA used in formulation of the adhesives had an Mn = 15.5 kDa and Mw/Mn = 1.4.