. Author manuscript; available in PMC: 2015 Jul 7.

Published in final edited form as: Chem Soc Rev. 2014 Apr 16;43(13):4368–4380. doi: 10.1039/c3cs60482a

Table 1.

Kang’s intramolecular carbonyl–allene coupling (2002).^a

Entry	Allene carbonyl	Product	Yield (%)
1	64	65	71
2	66	67	62
3	68	69	67
4	70	71	67

Reaction conditions: 1.0 equiv. of allene carbonyls, 1.1 equiv. of Me₃Si–SnBu₃ (17), 5 mol % of (π-allyl)₂Pd₂Cl₂, THF, room temperature, 10 min.